Ring closure of substituted 2 chlorosuccinates to or lactones has been studied by means of MP2/6 311+G(d,p)//MP2/6 31+G(d) calculations in water treated as a polarised continuum (PCM) and in vacuum. Optimised geometries have been obtained for 2 chlorosuccinate and its 2 methyl, 3,3 dimethyl, and 2,3,3 trimethyl derivatives, along with the transition structures and products for intramolecular nucleophilic displacement leading to the 3 or 4 membered rings. Relative enthalpies and Gibbs free energies of activation and reaction are presented, along with key geometrical parameters, and changes in electrostatic potential derived atomic charges.

This thesis examines how representations of Toronto in contemporary Canadian literature engage with place and further an understanding of spatial innovation in literature. Acknowledging the Canadian critical tradition of discussing place and space, the thesis moves the focus away from conventional engagements with wilderness motifs and small town narratives. In this way the thesis can be seen to respond to the nascent critical movement that urges engagement with contemporary urban spaces in Canadian literature.

The best series on Disney+ Hotstar come not from Disney+ or Hotstar, but rather HBO. In fact, more than half of the list below 44 to be precise come from the home of Game of Thrones. Disney+ Hotstar should probably be called HBO Go. A ce moment l, les luttes des femmes sont fortes, leurs actions multiples pour conqurir leurs droits et affirmer leurs liberts. Pourtant, c’est avec tonnement, scepticisme, hostilit parfois que certains accueillent cette initiative. Des fministes militantes dclarent mme prfrer les collections que les diteurs traditionnels se mettent alors leur proposer (pas pour longtemps, comme le prouvera la suite)..

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